Chemistry

Preparation and Properties of Carbon Dioxide

Chapter: Important Gases

Question 1 of 5 NDA MCQ

Which one of the following is the largest composition in biogas ?

Detailed Explanation

Correct Answer

βœ“ Option (b) is correct. Methane (CHβ‚„) constitutes the largest portion of biogas.

πŸ“– Governing Law / Core Concept

Biogas is primarily composed of methane (CHβ‚„) and carbon dioxide (COβ‚‚), generated through anaerobic digestion of organic matter.

πŸ§ͺ Step-by-Step Breakdown

The production of biogas can be represented by the following reaction:

\[ C_nH_m + O_2 \rightarrow CO_2 + H_2O + energy \]

During this process, for every mole of organic matter, methane is generated as the main product:

\[ C + 2H_2 \rightarrow CH_4 \]

Typical biogas composition is as follows:

  • Methane (CHβ‚„): 50-75%
  • Carbon Dioxide (COβ‚‚): 25-50%
  • Hydrogen (Hβ‚‚): 0-1%
  • Hydrogen Sulphide (Hβ‚‚S): < 1%

πŸ” Option Analysis

Other options consist of:

  • Carbon Dioxide (A): Major component but not as much as methane.
  • Hydrogen (C): Minimal presence in biogas.
  • Hydrogen Sulphide (D): Trace amounts, primarily a contaminant.

⚑ Mnemonic / Speed-Run

Remember this for biogas components: "Methane Might Command": Methane (75%) > Carbon Dioxide (50%) > Hydrogen (1%) > Hydrogen Sulfide (trace).

6. Visual Suggestion

6. Visual Suggestion

A chemical setup diagram showcasing the anaerobic digestion process with labeled gas compositions (methane and carbon dioxide) during biogas production will clarify the major components in a visual format.

πŸ“– Factual Verification & Reference

πŸ“– Factual Verification & Reference:

Verified against NCERT Class XII Chemistry, Chapter on Hydrocarbons and Biogas.

Question 2 of 5 NDA MCQ

At nearly 70Β° C, sodium bicarbonate shows the property of gradually decomposing, which makes it usable in bakery products. The product of decomposition responsible for this use of sodium bicarbonate is

Detailed Explanation

Correct Answer

βœ“ Option (a) is correct. The product responsible for the use of sodium bicarbonate in bakery products is carbon dioxide.

πŸ“– Governing Law / Core Concept

The decomposition of sodium bicarbonate (\( \text{NaHCO}_3 \)) upon heating is an example of thermal decomposition, where a single compound breaks down into two or more products.

πŸ§ͺ Step-by-Step Breakdown

Upon heating, sodium bicarbonate decomposes as follows:
\[ 2 \text{NaHCO}_3 (s) \rightarrow \text{Na}_2\text{CO}_3 (s) + \text{H}_2\text{O}(g) + \text{CO}_2(g) \]
This reaction produces sodium carbonate (\( \text{Na}_2\text{CO}_3 \)), water vapor (\( \text{H}_2\text{O} \)), and carbon dioxide (\( \text{CO}_2 \)). The gas released (carbon dioxide) is what makes baked goods rise.

πŸ” Option Analysis

  • B: Hydrogen - Not produced in this reaction.
  • C: Water vapour - Produced, but not the primary product that causes leavening.
  • D: Oxygen - Not involved in the decomposition of sodium bicarbonate.

⚑ Mnemonic / Speed-Run

Remember the decomposition of bicarbonate results in gas release: "Baking with Bicarb Makes Bubbles" (where bubbles refer to carbon dioxide).

6. Visual Suggestion

6. Visual Suggestion

A diagram showing the thermal decomposition of sodium bicarbonate: label states (\( \text{NaHCO}_3 \)), products (\( \text{Na}_2\text{CO}_3 \), \( \text{H}_2\text{O} \), and \( \text{CO}_2 \)), along with bubbles rising in dough.

πŸ“– Factual Verification & Reference

πŸ“– Factual Verification & Reference:

Verified against NCERT Class XI Chemistry, Chapter 1 (Stoichiometry and Chemical Reactions).

Question 3 of 5 NDA MCQ

Which one of the following is also known as dry ice in its solid form?

Detailed Explanation
βœ“

1. Correct Answer

Option B is correct. Dry ice is the solid form of carbon dioxide (CO2).

πŸ“– Short Explanation

Dry ice is the common name for solid carbon dioxide (CO2). It is used primarily as a cooling agent and is known for its ability to sublimate, transitioning from a solid to a gas without passing through a liquid phase.

πŸ’‘ 3. Why Correct Answer is Correct

Dry ice, which is solid carbon dioxide, is utilized in various industrial and scientific applications due to its properties. Unlike water ice, which melts into liquid water, dry ice sublimates directly from a solid to a gas. This occurs at temperatures below −78.5 °C (−109.3 °F) and is beneficial for refrigeration purposes where moisture is undesirable.
CO2(s) → CO2(g)

❌ 4. Why Other Options are Wrong

  • Option A: SiO2 refers to silicon dioxide, also known as silica, which is a chemical compound found in sand and quartz. It is not related to dry ice.
  • Option C: CaO, or calcium oxide, is commonly known as quicklime or lime. This substance is used in building materials, not as dry ice.
  • Option D: MgO stands for magnesium oxide, which is a white hygroscopic solid often used in medical applications or materials. It has no relation to dry ice.
⚑

NDA Speed-Run / Mnemonic Shortcut

To remember that dry ice is solid carbon dioxide, recall the mnemonic "D CO2," where "D" stands for dry and "CO2" is the chemical formula for carbon dioxide.

🎯

5. Key Learning Point

Dry ice is unique because it sublimates directly into carbon dioxide gas, avoiding the liquid phase entirely. This property is crucial for its use as a cooling agent.

6. Visual Suggestion

A diagrammatic representation showing a block of dry ice (CO2 solid) sublimating into carbon dioxide gas (CO2 gas) can help visualize the transition. Additionally, a temperature scale highlighting the point of sublimation at -78.5 °C will reinforce understanding.

Question 4 of 5 NDA MCQ

 What is the colour of the precipitate obtained by passing COβ‚‚ gas through lime water?

Detailed Explanation

Correct Answer

βœ“ Option C is correct. The precipitate formed is white.

πŸ“– Governing Law / Core Concept

The reaction involves the formation of calcium carbonate from carbon dioxide and calcium hydroxide. The reaction can be classified as a precipitation reaction.

πŸ§ͺ Step-by-Step Breakdown

The chemical reaction of passing COβ‚‚ through lime water (calcium hydroxide solution) is as follows:

\[ \text{Ca(OH)}_2 (aq) + \text{CO}_2 (g) \rightarrow \text{CaCO}_3 (s) + \text{H}_2\text{O} (l) \]

Here, calcium carbonate \((\text{CaCO}_3)\) is formed as a precipitate, which appears white in color.

πŸ” Option Analysis

Other options include

  • A: Green - Not applicable, as no green compounds are formed.
  • B: Blue - Incorrect, no blue precipitate is created in this reaction.
  • D: Brown - No browning occurs; the precipitate is distinctly white.

⚑ Mnemonic / Speed-Run

Remember: COβ‚‚ + Ca(OH)β‚‚ gives you "C" for "Calcium" followed by "W" for "White" (CaCO₃ precipitate).

6. Visual Suggestion

6. Visual Suggestion

A diagram demonstrating the reaction setup: a flask with lime water, COβ‚‚ gas input, and the resulting white precipitation of CaCO₃. This could show before and after states for clarity.

πŸ“– Factual Verification & Reference

πŸ“– Factual Verification & Reference:

Verified against NCERT Class 12 Chemistry, Chapter 1 (Some Basic Concepts of Chemistry).

Question 5 of 5 NDA MCQ

Which one of the following will NOT produce carbon dioxide on reacting with an aqueous solution of hydrochloric acid ?

Detailed Explanation

Correct Answer

βœ“ Option (b) is correct. Quick Lime does not produce carbon dioxide with hydrochloric acid.

πŸ“– Governing Law / Core Concept

The reaction of acids with carbonates and bicarbonates generally results in the production of carbon dioxide. The fundamental reaction can be represented as follows:

\[ \text{CaCO}_3 + 2 \text{HCl} \rightarrow \text{CaCl}_2 + \text{CO}_2 + \text{H}_2\text{O} \]

πŸ§ͺ Step-by-Step Breakdown

Let's analyze the options:

  • A: Limestone (CaCO3) - Reacts with HCl:
  • \[ \text{CaCO}_3 + 2 \text{HCl} \rightarrow \text{CaCl}_2 + \text{CO}_2 + \text{H}_2\text{O} \]
  • C: Chalk (CaCO3) - Identical to Limestone:
  • \[ \text{CaCO}_3 + 2 \text{HCl} \rightarrow \text{CaCl}_2 + \text{CO}_2 + \text{H}_2\text{O} \]
  • D: Marble (CaCO3) - Again, behaves like Limestone:
  • \[ \text{CaCO}_3 + 2 \text{HCl} \rightarrow \text{CaCl}_2 + \text{CO}_2 + \text{H}_2\text{O} \]
  • B: Quick Lime (CaO) - Does not contain carbonate.
  • \[ \text{CaO} + 2 \text{HCl} \rightarrow \text{CaCl}_2 + \text{H}_2\text{O} \]

πŸ” Option Analysis

  • A: Limestone - Produces CO2.
  • B: Quick Lime - Does not produce CO2.
  • C: Chalk - Produces CO2.
  • D: Marble - Produces CO2.

⚑ Mnemonic / Speed-Run

Remember that substances containing carbonate (CaCO3) will produce carbon dioxide upon reaction with hydrochloric acid.

πŸ“– Factual Verification & Reference

πŸ“– Factual Verification & Reference:

Verified against NCERT Class XII Chemistry Curriculum, Chapter on Acids and Bases.

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