Chemistry

Oxidation and Reduction

Chapter: Chemical Reactions and Equations

Question 1 of 5 NDA MCQ

 Which one of the following is not an example ofa redox reaction?

Detailed Explanation

Correct Answer

✓ Option A is correct. It does not involve a change in oxidation states, hence, not a redox reaction.

📖 Core Concept

Redox reactions involve the transfer of electrons, leading to changes in oxidation states of reactants. The general equation governing redox reactions can be represented as:

Oxidation: \( \text{Zn} \rightarrow \text{Zn}^{2+} + 2e^- \)

Reduction: \( \text{Cu}^{2+} + 2e^- \rightarrow \text{Cu} \)

🧪 Step-by-Step Breakdown

The evaluation of each option determines if they are redox reactions:

  • Option A: AlCl₃ + 3H₂O → Al(OH)₃ + 3HCl
  • No change in oxidation states:

    Oxidation State of Al: +3 (both sides)

    Oxidation State of Cl: -1 (both sides)

  • Option B: 2NaH → 2Na + H₂
  • Redox Reaction:

    Oxidation: \( \text{Na}^{+} \rightarrow \text{Na}^0 \)

    Reduction: \( \text{H}^0 \rightarrow \text{H}_2 \)

  • Option C: 4Fe + 3O₂ → 2Fe₂O₃
  • Redox Reaction:

    Oxidation: \( \text{Fe}^0 \rightarrow \text{Fe}^{+3} \)

    Reduction: \( \text{O}_2^{0} \rightarrow \text{O}^{-2} \)

  • Option D: CuSO₄ + Zn → Cu + ZnSO₄
  • Redox Reaction:

    Oxidation: \( \text{Zn}^0 \rightarrow \text{Zn}^{+2} \)

    Reduction: \( \text{Cu}^{+2} \rightarrow \text{Cu}^0 \)

🔍 Option Analysis

Options B, C, and D are valid redox reactions as they involve changes in oxidation states, while Option A is an acid-base reaction (no change in oxidation states).

⚡ Mnemonic / Speed-Run

Mnemonic: "LEO says GER" — Lose Electrons Oxidation, Gain Electrons Reduction.

6. Visual Suggestion

6. Visual Suggestion

A comparison table showing each reaction and pointing out oxidation states for reactants and products would clarify the nature of redox reactions.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class 11 Chemistry, Chapter 8 (Redox Reactions).

Question 2 of 5 NDA MCQ

Which one of the following statements is NOT correct for the given reaction?

Fe(s) + CuSO₄(aq) → FeSO₄(aq) + Cu(s)

Detailed Explanation

Correct Answer

✓ Option C is correct. Copper is less reactive than iron.

📖 Governing Law / Core Concept

The reaction follows the principles of the reactivity series of metals. Iron displaces copper from copper sulfate solution, indicating that iron is more reactive.

🧪 Step-by-Step Breakdown

In the reaction:

\[ \text{Fe}(s) + \text{CuSO}_4(aq) \rightarrow \text{FeSO}_4(aq) + \text{Cu}(s) \]

Here, iron (Fe) oxidizes to Fe²⁺ and reduces Cu²⁺ to Cu. Thus:

  • Iron acts as a reducing agent.
  • The resulting solution of FeSO₄ turns green due to iron ions.
  • Copper is less reactive compared to iron.
  • This is a redox reaction.

🔍 Option Analysis

  • A: Iron is the reducing agent - correct.
  • B: The solution turns green - correct.
  • C: Copper is a more reactive metal than iron - incorrect.
  • D: It is a redox reaction - correct.

⚡ Mnemonic / Speed-Run

Remember, "Higher on the list, easier to displace" for reactivity series of metals.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XII Chemistry Chapter 7 (Redox Reactions).

Question 3 of 5 NDA MCQ

Hydrogenation of vegetable oils using nickel catalyst is an example of

Detailed Explanation

Correct Answer

✓ Option C is correct. The hydrogenation of vegetable oils is an addition reaction.

📖 Governing Law / Core Concept

In organic chemistry, an addition reaction involves the addition of one or more atoms or groups to a molecule without the loss of any atom from it.

🧪 Step-by-Step Breakdown

Vegetable oils, composed mainly of unsaturated fatty acids, undergo hydrogenation to form saturated fats. This process is typically represented by the equation:
\[ \text{C}_n\text{H}_{2n-2} + \text{H}_2 \xrightarrow{\text{Ni}} \text{C}_n\text{H}_{2n} \]
Here, \( \text{C}_n\text{H}_{2n-2} \) represents unsaturated fatty acids and \( \text{C}_n\text{H}_{2n} \) is the resultant saturated fatty acid (vegetable ghee). The nickel catalyst facilitates this addition by breaking the double bonds in the unsaturated hydrocarbons.

🔍 Option Analysis

- **A: Substitution reaction:** Involves the replacement of an atom in a molecule. - **B: Elimination reaction:** Involves the loss of atoms to form a double bond. - **D: Free-radical polymerization:** A process involving the reaction of monomers that form polymers.

⚡ Mnemonic / Speed-Run

Remember: "Addition is for hydrogenation!" to quickly recall that hydrogenation leads to addition reactions.

6. Visual Suggestion

6. Visual Suggestion

Consider a diagram showing the structure of vegetable oils (unsaturated) transitioning into vegetable ghee (saturated) through the process of hydrogenation, highlighting the breaking of double bonds.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XI Chemistry, Chapter on Organic Chemistry: Hydrocarbons.

Question 4 of 5 NDA MCQ

In the following redox reaction, which compound is acting as a reducing agent?

         N2H4 + 2H2O2 → N2 + 4H2O

Detailed Explanation

Correct Answer

✓ Option B is correct. N2H4 acts as the reducing agent by losing electrons.

📖 Governing Law / Core Concept

The reaction follows the principles of redox chemistry, where reducing and oxidizing agents are defined based on electron transfer. Here, N2H4 (hydrazine) undergoes oxidation while H2O2 (hydrogen peroxide) serves as the oxidizing agent.

🧪 Step-by-Step Breakdown

The given reaction:

\[ N_2H_4 + 2H_2O_2 \rightarrow N_2 + 4H_2O \]

Analyzing oxidation states:

  • Oxidation state of N in N2H4: -2
  • Oxidation state of N in N2: 0
  • Oxidation state of O in H2O2: -1
  • Oxidation state of O in H2O: -2

Change in oxidation states signifies:

  • From -2 (N2H4) to 0 (N2): N2H4 is oxidized.
  • O in H2O2 goes from -1 to -2: H2O2 is reduced.

Conclusion: N2H4 is acting as the reducing agent.

🔍 Option Analysis

  • H2O2: Acts as the oxidizing agent, gaining electrons.
  • N2: Product of reduction, not an agent.
  • H2O: Also a product, no redox role.

⚡ Mnemonic / Speed-Run

Remember: "OIL RIG" - Oxidation Is Loss, Reduction Is Gain. N2H4 loses electrons, hence it is oxidized.

6. Visual Suggestion

6. Visual Suggestion

A flowchart illustrating the electron transfer and changes in oxidation states during the reaction between N2H4 and H2O2 would clarify the redox processes involved, highlighting the roles of reducing and oxidizing agents.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XII Chemistry, Chapter on Redox Reactions.

Question 5 of 5 NDA MCQ

Which one of the following statements regarding oxidation and reduction reaction is NOT correct?

Detailed Explanation

1. Correct Answer

Option A is correct. The incorrect statement is that losing hydrogen refers to oxidation, not reduction.

📖 Short Explanation

The processes of oxidation and reduction involve changes in the gain or loss of elements like oxygen or hydrogen, or electrons. This question tests the conceptual understanding of how these reactions affect compounds.

💡 3. Why Correct Answer is Correct

Oxidation and reduction (redox reactions) are essential chemical reactions. Oxidation involves the gain of oxygen or the loss of hydrogen and electrons:
Oxidation: Loss of H2, Gain of O2
Reduction involves the gain of hydrogen or the loss of oxygen and gaining electrons:
Reduction: Gain of H2, Loss of O2

4. Why Other Options are Wrong

  • Option B: This is correct. Loss of oxygen results in reduction (reducing the oxidation state).
  • Option C: This is correct, gaining hydrogen leads to reduction.
  • Option D: This is correct, gaining oxygen implies oxidation (increasing the oxidation state).

NDA Speed-Run / Mnemonic Shortcut

Use 'OIL RIG' as a mnemonic: "Oxidation Is Loss, Reduction Is Gain" of electrons.

🎯

5. Key Learning Point

Oxidation and reduction definitions: oxidation is loss of electrons/hydrogen or gain of oxygen; reduction is gain of electrons/hydrogen or loss of oxygen.

6. Visual Suggestion

A diagram illustrating a molecule, highlighting changes when it undergoes oxidation with oxygen atoms being attached, and reduction with hydrogen atoms being added or oxygen atoms being removed.

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