Chemistry

Simple Chemical Equations

Chapter: Chemical Reactions and Equations

Question 1 of 5 NDA MCQ

Which one of the following reactions is an example of decomposition reactions?

Detailed Explanation

Correct Answer

✓ Option B is correct. This reaction represents a decomposition reaction.

📖 Governing Law / Core Concept

A decomposition reaction involves the breakdown of one compound into two or more substances, usually requiring energy input (heat, light, or electricity).

🧪 Step-by-Step Breakdown

In the reaction:

\[ 2AgCl(s) \xrightarrow{sunlight} 2Ag(s) + Cl_2(g) \]

Silver chloride (AgCl) decomposes upon exposure to light, yielding solid silver (Ag) and chlorine gas (Cl₂). Observation includes color change from white to grayish black for silver.

🔍 Option Analysis

  • A: Combustion of methane; does not decompose a single reactant.
  • C: Redox reaction producing copper and water; not a decomposition.
  • D: Single displacement reaction; iron displaces copper in copper(II) sulfate.

⚡ Mnemonic / Speed-Run

Remember: "Decompose means to break down!" to distinguish decomposition from other reaction types.

6. Visual Suggestion

6. Visual Suggestion

A flowchart illustrating decomposition reactions can help visualize how one reactant splits into multiple products. Include examples and energy requirements.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XI Chemistry, Chapter 1 (Basic Concepts of Chemistry).

Question 2 of 5 NDA MCQ

Which one of the following reactions does not result in the evolution of hydrogen gas?

Detailed Explanation

Correct Answer

✓ Option (b) is correct. Mixing water with Plaster of Paris does not evolve hydrogen gas.

📖 Governing Law / Core Concept

The reaction of certain metals and acids results in the evolution of hydrogen gas, which is governed by the reactivity of metals with acids and the nature of chemical reactions.

🧪 Step-by-Step Breakdown

Analyzing each option:

  • A: Zinc (Zn) reacts with dilute sulphuric acid (H₂SO₄) to produce hydrogen gas.
  • \[ Zn + H_2SO_4 \rightarrow ZnSO_4 + H_2\uparrow \]
  • C: Heating zinc metal with sodium hydroxide (NaOH) releases hydrogen gas.
  • \[ Zn + 2NaOH + 2H_2O \rightarrow Na_2[Zn(OH)_4] + H_2\uparrow \]
  • D: Potassium (K) reacts vigorously with water to produce hydrogen gas.
  • \[ 2K + 2H_2O \rightarrow 2KOH + H_2\uparrow \]
  • B: Mixing water with Plaster of Paris (Calcium Sulphate Hemihydrate) does not involve any metal displacement or hydrogen evolution.
  • \[ CaSO_4 \cdot \frac{1}{2}H_2O + H_2O \rightarrow CaSO_4 \cdot 2H_2O \

🔍 Option Analysis

Options A, C, and D involve reactions that result in hydrogen gas production, whereas option B merely hydrates the Plaster of Paris without any gas evolution.

⚡ Mnemonic / Speed-Run

Remember: "Zinc and Acid, Potassium and Water, Sodium too - all give hydrogen, but Plaster's just glue!"

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class 11 Chemistry, Chapter 14 (Chemical Kinetics).

Question 3 of 5 NDA MCQ

In electrolytic refining of copper, the electrolyte is a solution of

Detailed Explanation

Correct Answer

✓ Option B is correct. The electrolyte for electrolytic refining of copper is acidified copper sulfate.

📖 Governing Law / Core Concept

Electrolytic refining is based on the principle of electrolysis where an electric current is passed through a solution to separate and purify metal ions.

🧪 Step-by-Step Breakdown

In the electrolytic refining of copper:

  • Anode: Impure copper (Cuimp) dissolves during the electrolysis, releasing copper ions (Cu2+). This is represented by the reaction:
  • \[ \text{Cu}_{\text{imp}} \rightarrow \text{Cu}^{2+} + 2 \text{e}^- \]
  • Cathode: Pure copper is deposited from the copper ions in the electrolyte, shown as:
  • \[ \text{Cu}^{2+} + 2 \text{e}^- \rightarrow \text{Cu}_{\text{pure}} \]
  • Electrolyte: Acidified copper sulfate (\( \text{CuSO}_4 \)) facilitates the movement of copper ions. The addition of sulfuric acid (H2SO4) enhances conductivity.
  • Color Observation: The blue color of the copper sulfate solution fades as copper ions deposit at the cathode.

🔍 Option Analysis

  • Option A: Acidified copper chloride does not serve as a suitable electrolyte in copper refining.
  • Option C: Potassium chloride is not relevant for copper purification.
  • Option D: Sodium sulfate is also ineffective as an electrolyte for the process.

⚡ Mnemonic / Speed-Run

Remember: "Copper Soaks Easily" refers to the use of Copper Sulfate as the electrolyte in the refining process.

📊 Visual Suggestion

6. Visual Suggestion

A simplified electrolysis setup diagram showing the anode (impure copper), cathode (pure copper), and the flow of current through acidified copper sulfate electrolyte, including color changes and ion movements.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XII Chemistry, Chapter 6 (General Principles and Processes of Isolation of Elements).

Question 4 of 5 NDA MCQ

Which one of the following is an endothermic reaction?

Detailed Explanation

Correct Answer

✓ Option (d) is correct. The decomposition of lead(II) nitrate is an endothermic reaction, absorbing heat.

📖 Governing Law / Core Concept

The decomposition reaction of some compounds, like metal nitrates, typically requires energy input (heat), indicating an endothermic process.

🧪 Step-by-Step Breakdown

The decomposition of lead(II) nitrate is represented as:

\[ 2 \text{Pb(NO}_3\text{)}_2 (s) \rightarrow 2 \text{PbO} (s) + 4 \text{NO}_2 (g) + \text{O}_2 (g) \]

This reaction absorbs heat, illustrated through the thermal properties noticed in laboratory settings.

🔍 Option Analysis

  • A: \(\text{CH}_4(g) + 2\text{O}_2(g) \rightarrow \text{CO}_2(g) + 2\text{H}_2\text{O}(l)\) - This is an exothermic combustion reaction.
  • B: \(\text{C}_6\text{H}_{12}\text{O}_6(aq) + 6\text{O}_2(g) \rightarrow 6\text{CO}_2(g) + 6\text{H}_2\text{O}(l)\) - Also an exothermic biological oxidation reaction.
  • C: \(\text{N}_2(g) + 3\text{H}_2(g) \rightarrow 2\text{NH}_3(g)\) - A synthesis reaction that releases energy.

⚡ Mnemonic / Speed-Run

  • Endothermic AIS: Absorb, Inputs heat, Skills temperature.

6. Visual Suggestion

6. Visual Suggestion

A table comparing endothermic and exothermic reactions: showcasing energy changes, examples of reactions, and thermal observation outcomes.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XII Chemistry, Chapter 1 (Thermodynamics).

Question 5 of 5 NDA MCQ

Match List I with List II and select the answerusing the code given below the Lists:

Detailed Explanation

Correct Answer

✓ Option C is correct. The reactions are matched accurately based on their types.

📖 Governing Law / Core Concept

Types of chemical reactions can be classified as Single displacement, Double displacement, Combination, and Decomposition reactions.

🧪 Step-by-Step Breakdown

  • A. CaO(s) + H2O(l) → Ca(OH)2(aq): Combination Reaction
  • B. CaCO3(s) → CaO(s) + CO2(g): Decomposition Reaction
  • C. Pb(s) + CuCl2(aq) → PbCl2(aq) + Cu(s): Single Displacement Reaction
  • D. Na2SO4(aq) + BaCl2(aq) → BaSO4(s) + 2NaCl(aq): Double Displacement Reaction

🔍 Option Analysis

  • Option A matches 2 (Single displacement) incorrectly.
  • Option B matches 4 (Decomposition) incorrectly.
  • Option D matches 3 (Combination) incorrectly.

⚡ Mnemonic / Speed-Run

Mnemonic for Reaction Types: CDSD - Combination, Decomposition, Single displacement, Double displacement.

6. Visual Suggestion

Visual Suggestion

A table comparing the four types of chemical reactions with examples and visuals of the reactants and products would aid memory and understanding.

📖 Factual Verification & Reference

📖 Factual Verification & Reference:

Verified against NCERT Class XI Chemistry, Chapter on Chemical Reactions.

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