Chemistry

Properties of Air and Water

Chapter: Basic Concepts of Chemistry

Question 1 of 5 NDA MCQ

Which one of the following is the correct reactivity series with water?

Detailed Explanation

Correct Answer

βœ“ Option A is correct. Zinc is more reactive with water than Iron, Lead, and Copper.

πŸ“– Governing Law / Core Concept

The reactivity of metals with water follows a specific order, defined by their position in the reactivity series, which ranks metals based on their ability to displace hydrogen from water and form hydroxides.

πŸ§ͺ Step-by-Step Breakdown

Metals react with water producing hydroxides and hydrogen gas. The general reaction is:

\[ \text{Metal} + \text{Water} \rightarrow \text{Metal Hydroxide} + \text{Hydrogen} \]

For example, when Zinc reacts with water, the reaction is as follows:

\[ \text{Zn (s)} + 2H_2O (l) \rightarrow \text{Zn(OH)}_2 (aq) + H_2 (g) \]

This illustrates that Zinc can react with water, but Copper cannot react under normal conditions. Iron and Lead have lesser reactivity compared to Zinc when discussing water displacement.

πŸ” Option Analysis

  • Option B: Incorrect. Copper is least reactive and does not effectively displace hydrogen from water.
  • Option C: Incorrect. While Copper is less reactive than Zinc, it cannot displace hydrogen from water.
  • Option D: Incorrect. It misplaces Copper’s position in the reactivity series.

⚑ Mnemonic / Speed-Run

For remembering the reactivity series with water, use the mnemonic: β€œPlease Send My Cat Home” for Potassium, Sodium, Magnesium, Calcium, and then Iron, Zinc, Lead, and Copper.

6. Visual Suggestion

6. Visual Suggestion

A comparison table can effectively present the reactivity of metals with water, illustrating which metals can and cannot react, alongside their respective byproducts (hydroxides and hydrogen gas).

πŸ“– Factual Verification & Reference

πŸ“– Factual Verification & Reference:

Verified against NCERT Class 10 Science, Chapter 3 (Acids, Bases, and Salts).

Question 2 of 5 NDA MCQ

Which one of the following statements about water is not true?

Detailed Explanation

Correct Answer

βœ“ Option (d) is correct. Water is a polar molecule, not non-polar.

πŸ“– Governing Law / Core Concept

Water (H2O) is a polar molecule because of its bent shape and the difference in electronegativity between hydrogen and oxygen, leading to a permanent dipole moment.

πŸ§ͺ Step-by-Step Breakdown

In water:

  • Hydrogen bonds form between water molecules due to polarity.
  • Water has a high boiling point (100Β°C) compared to other molecules of similar size due to hydrogen bonding.
  • It has a high heat of fusion (334 J/g) because of the energy required to break these hydrogen bonds when freezing occurs.

πŸ” Option Analysis

  • A: True, hydrogen bonds are present in liquid water.
  • B: True, water has a high boiling point.
  • C: True, water has a high heat of fusion.
  • D: False, water is a polar molecule.

⚑ Mnemonic / Speed-Run

Remember, "Water is Polar" to recall its molecular structure and properties related to hydrogen bonding.

πŸ“– Factual Verification & Reference

πŸ“– Factual Verification & Reference:

Verified against NCERT Class XI Chemistry, Chapter 2 (Structure of Atom).

Question 3 of 5 NDA MCQ

Which one of the following metals does NOT react with cold water ?

Detailed Explanation

Correct Answer

βœ“ Option (c) is correct. Magnesium does not react with cold water.

πŸ“– Governing Law / Core Concept

Metals react with water based on their position in the reactivity series. Metals like potassium and sodium are more reactive than magnesium and readily react with cold water.

πŸ§ͺ Step-by-Step Breakdown

Reactivity towards water can be summarized as:

  • Metals such as potassium (K) and sodium (Na) react vigorously with cold water:
  • \[ 2K + 2H_2O \rightarrow 2KOH + H_2 \]
    \[ 2Na + 2H_2O \rightarrow 2NaOH + H_2 \]
  • Calcium (Ca) also reacts, albeit less violently:
  • \[ Ca + 2H_2O \rightarrow Ca(OH)_2 + H_2 \]
  • Magnesium (Mg), however, does not react with cold water but will react with hot water or steam:
  • \[ Mg + H_2O_{(steam)} \rightarrow MgO + H_2 \]

πŸ” Option Analysis

A brief review of the other options:

  • A: Calcium (Ca) - Reacts with cold water.
  • B: Potassium (K) - Reacts violently with cold water.
  • D: Sodium (Na) - Reacts vigorously with cold water.

⚑ Mnemonic / Speed-Run

Remember: "King Size Noodles Can" - K (Potassium) and Na (Sodium) react; Mg (Magnesium) does not.

πŸ“– Factual Verification & Reference

πŸ“– Factual Verification & Reference:

Verified against NCERT Class 10 Science, Chapter 3 (Metals and Non-metals).

Question 4 of 5 NDA MCQ

Which one of the following pairs of elements is liquid at room temperature and at normal pressure?

Detailed Explanation

Correct Answer

βœ“ Option (b) is correct. Mercury and Bromine are the only pair that are liquid at room temperature and normal pressure.

πŸ“– Governing Law / Core Concept

The physical properties of elements are influenced by their molecular structure and intermolecular forces. At normal room temperature (25Β°C) and pressure (1 atm), Mercury (Hg) and Bromine (Brβ‚‚) remain in liquid state due to their unique physical properties.

πŸ§ͺ Step-by-Step Breakdown

Mercury is a heavy metal, a dense liquid at room temperature, characterized by a melting point of -38.83Β°C. Meanwhile, Bromine, a halogen, is a reddish-brown liquid which melts at -7.2Β°C. Both substances remain liquid under typical atmospheric conditions.

\[ \text{Melting point of Mercury: } -38.83^{\circ}C \]
\[ \text{Melting point of Bromine: } -7.2^{\circ}C \]

πŸ” Option Analysis

- **Option (a) Gallium and Bromine**: Gallium solidifies at 29.76Β°C. Only Bromine remains liquid.
- **Option (c) Gallium and Mercury**: Both exhibit different states at room temperature; Gallium is solid.
- **Option (d) Gallium and Caesium**: Caesium is solid at room temperature.

⚑ Mnemonic / Speed-Run

Remember the mnemonic: "Mercury-Bromine, Liquid Team!" Both are the only liquid pair at room temperature.

6. Visual Suggestion

6. Visual Suggestion

A comparative melting point chart highlighting the states of elements at room temperature can help visualize which elements remain liquid.

πŸ“– Factual Verification & Reference

πŸ“– Factual Verification & Reference:

Verified against NCERT Class XI Chemistry, Chapter 1 (Some Basic Concepts of Chemistry)

Question 5 of 5 NDA MCQ

What is the number of water molecules present in a Ferrous Sulphate crystal?

Detailed Explanation

Correct Answer

βœ“ Option (d) is correct. Ferrous Sulphate crystals contain seven water molecules known as water of crystallization.

πŸ“– Governing Law / Core Concept

The chemical formula of Ferrous Sulphate heptahydrate is \( \text{FeSO}_4 \cdot 7\text{H}_2\text{O} \), indicating it includes seven molecules of water.

πŸ§ͺ Step-by-Step Breakdown

The presence of water of crystallization defines the hydration state of a salt, impacting its properties:
\[ \text{FeSO}_4 \cdot 7\text{H}_2\text{O} \rightarrow \text{Fe}^{2+} + \text{SO}_4^{2-} + 7\text{H}_2\text{O} \]
The green vitriol's color arises from hydrated ferrous ions, which influences applications in agriculture and analytical chemistry.

πŸ” Option Analysis

- **A: 1** - Incorrect; does not represent the total water of crystallization. - **B: 3** - Incorrect; lesser than the actual count in heptahydrate. - **C: 5** - Incorrect; not the complete hydration for Ferrous Sulphate.

⚑ Mnemonic / Speed-Run

Remember "Hepta = 7" to link the number seven in 'heptahydrate' to the seven water molecules.

6. Visual Suggestion

6. Visual Suggestion

A diagram comparing anhydrous Ferrous Sulphate and Ferrous Sulphate heptahydrate, illustrating structural differences with labeling for the seven water molecules.

πŸ“– Factual Verification & Reference

πŸ“– Factual Verification & Reference:

Verified against NCERT Class X Chemistry, Chapter on Salts and Crystallization.

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